The first paper was on the catalysis of aromatic hydrogen-deuterium exchange by metal hydrides.
2.
Using this technique the resolution of deuterium exchange is determined by the size of the peptides produced during digestion.
3.
He developed methods for gas phase hydrogen-deuterium exchange, substitution and elimination reactions, and comparisons of gas and solution phase reaction energetics.
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For example, the location and relative amount of deuterium exchange along the peptide backbone can be determined roughly by subjecting the protein to proteolysis after the exchange reaction has been quenched.
5.
Infrared spectroscopy is rarely used, since the ?-helical spectrum resembles that of a random coil ( although these might be discerned by, e . g ., hydrogen-deuterium exchange ).
6.
Contrary to crystal structures of active thrombin, hydrogen-deuterium exchange mass spectrometry studies indicate that this N-terminal Ile-NH3 does not become inserted into the ?-barrel in the apo form of thrombin.
7.
Protein folding is routinely studied using NMR spectroscopy, for example by monitoring hydrogen-deuterium exchange of backbone amide protons of proteins in their native state, which provides both the residue-specific stability and overall stability of proteins.
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"' Hydrogen deuterium exchange "': A method growing in popularity which gives information about the solvent accessibility of various parts of the antigen and the antibody, demonstrating reduced solvent accessibility where protein to protein interactions occur.
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The pKa lies somewhere between the alcohol hydrogen and the amine hydrogen, which means such a hydrogen will behave chemically somewhere between that of alcohols and amines, and should undergo deuterium exchange .-- 32 " "'03 : 47, 24 September 2009 ( UTC)
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:: : : : : Hmmmm, I think you're looking for the " hydrogen exchange rate " or perhaps " proton exchange rate ", " hydrogen-deuterium exchange rate " etc . Looks like might be useful but I haven't accessed; the first abstract says OH-exchange predominates ( for water in organic solvents ).
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